FT-IR SPECTRUM ANALYSIS OF ANIONITE OBTAINED BY MODIFICATION OF POLYVINYL CHLORIDE WITH UREA
Keywords:
PVC, modification, urea, anionite.Abstract
It is known that polyvinyl chloride, along with polyethylene and polypropylene, is the most important large-tonnage cheap construction polymer. For this reason, the amount of its waste is constantly increasing. One of the ways to solve this problem is the chemical modification of PVC through polymer transformations. This review discusses the conditions for synthesizing anionite by modifying PVC with urea. As a result of the study of the influence of various external factors on the modification of polyvinyl chloride with urea in the production of anionites, the optimal conditions for the modification of polyvinyl chloride with modifiers were determined, the optimal mass ratio of polymer and modifier was 1:5 mass ratio, the optimal temperature of the reaction medium was 433 K, respectively for the synthesis of PPE-2 , the acceptable time for the duration of the modification was set to 8 hours.
References
.S. Moulay, Chemical modifikacion of poly(vinly chloride)-Still on the run. Progress in Polymer Scence 35(2010) 303-331
.Li, Zhili. Synthesis of a carbamide-based dithiocarbamate chelator for the removal of heavy metal ions from aqueous solutions. Journal of Industrial and Engineering Chemistry, 2014. 20(2), 586–590 pp.
.Diniz C.V., Doyle F.M., Martins A.H. Uptake of heavy metals by chelating resins from acidic manganese chloride solution, Minerals Metallurgy Processing, 2000; Vol. 17, pp. 217-222.
. Mukhamediev, M.G., Bekchanov, D.Z. New Anion Exchanger Based on Polyvinyl Chloride and Its Application in Industrial Water Treatment. Russ J Appl Chem 92, 1499–1505 (2019). https://doi.org/10.1134/S1070427219110053.
. Davron B, Mukhtar M, Nurbek K, Suyun X, Murod J. Synthesis of a new granulated polyampholyte and its sorption properties. Int J Technol. 2020; 11(4):794-803. https://doi.org/10.14716/ijtech.v11i4. 4024.
. Bekchanov, D., Mukhamediev, M.,Babojonova, G., Lieberzeit, P., & Su, X. (2023). Anion exchange material based on polyvinylchloride and urea for the removal of chromium(VI) ions from aqueous solutions. CLEAN - Soil, Air,Water, 2200411. https://doi.org/10.1002/clen.202200411
. Himoyat I, Shodlik K, Mukhtarjan M, Davronbek B, Sherimmat Y, and Bakhtiyor Y. Sorption of Zn (II) and Cr (III) ions into ion exchangers obtained on the polyvinylchloride. Int J Pharm Res. 2020; 12:1728- 1738. https://doi.org/10.31838/ijpr/2020.12.03.236.
. Mukhamediev, M.G., Bekchanov, D.Z. New Anion Exchanger Based on Polyvinyl Chloride and Its Application in Industrial Water Treatment. Russ J Appl Chem 92, 1499–1505 (2019). https://doi.org/10.1134/S1070427219110053.